From Dichlorocyclopropanes to Furans and Cyclopentadienes via Vinylcarbenes
Base-induced elimination of dichlorocarbene adducts 2 to 9-alkoxyphenanthrenes 1 leads to furans 6, presumably via cyclopropenes 3 which undergo rearrangement to vinylcarbenes 4 and C-H insertion.By the same sequence, the 9-substituted alkylphenanthrene a
Mueller, Paul,Pautex, Nicole
p. 1630 - 1637
(2007/10/02)
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