Metal amides as the simplest acid/base catalysts for stereoselective carbon-carbon bond-forming reactions
In this paper, new possibilities for metal amides are described. Although typical metal amides are recognized as strong stoichiometric bases for deprotonation of inert or less acidic hydrogen atoms, transition-metal amides, namely silver and copper amides
Yamashita, Yasuhiro,Kobayashi, Shu
p. 9420 - 9427
(2013/07/26)
Chiral silver amides as effective catalysts for enantioselective [3+2] cycloaddition reactions
Asymmetric [3+2] cycloaddition of α-aminoester Schiff bases with substituted olefins is one of the most efficient methods for the preparation of chiral pyrrolidine derivatives in optically pure form. In spite of its potential utility, applicable substrate
Yamashita, Yasuhiro,Imaizumi, Takaki,Guo, Xun-Xiang,Kobayashi, Shu
supporting information; experimental part
p. 2550 - 2559
(2012/06/18)
Chiral silver amide-catalyzed enantioselective [3 + 2] cycloaddition of α-aminophosphonates with olefins
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Yamashita, Yasuhiro,Guo, Xun-Xiang,Takashita, Ryuta,Kobayashi, Shu
supporting information; experimental part
p. 3262 - 3263
(2010/05/01)
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