The Chemistry of N-Substituted Benzotriazoles. Part 20. Mono-N-t-Butylation of Aromatic and Heteroaromatic Amines
Adducts R1CH(Bt)NHAr, readily available from aldehydes, primary aromatic or heteroaromatic amines, and benzotriazole are converted by H2O2-SeO2 into mixtures of R1CONHAr and HCONR1Ar in proportions which depend rationally on the nature of the R1 group.For R1=But, the formamide HCON(But)Ar is formed in satisfactory yields thus enabling the title reaction to be achieved.
Katritzky, Alan R.,Eynde, Jean-Jacques Vanden
p. 639 - 642
(2007/10/02)
More Articles about upstream products of 121953-47-7