A short biomimetic synthesis of the meroterpenoids guajadial and psidial A
The biosynthesis of the meroterpenoid guajadial was previously hypothesized to occur via a hetero-Diels-Alder reaction between caryophyllene and an o-quinone methide. This hypothesis has been verified via the biomimetic synthesis of guajadial and psidial A in an aqueous three-component coupling reaction, between caryophyllene, benzaldehyde, and diformylphloroglucinol.
Lawrence, Andrew L.,Adlington, Robert M.,Baldwin, Jack E.,Lee, Victor,Kershaw, Jessica A.,Thompson, Amber L.
supporting information; experimental part
p. 1676 - 1679
(2010/10/19)
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