Oxidative dearomatization: Synthesis of functionalized bicyclo[2.2.2]octenones, sigmatropic shift in excited state, and radical-induced cleavage of cyclopropane ring
Synthesis of novel bicyclo[2.2.2]octenones endowed with a β,γ-enone system in which γ-carbon is substituted with an electron-withdrawing group from simple aromatics is described. Oxa-di-pi-methane reaction of bicyclo[2.2.2]octenones to functionalized bicy
Modulation of the luminescence quantum efficiency for blue luminophor {Al(salophen)}+ by ester-substituents
A series of AlIII complexes of a salophen (N,N′- bis(salicylidene)-o-phenylenediamine) derivative with an ester substituent at the C5 position of the salicylidene rings have been prepared and their luminescence properties investigated. All exhi