Synthesis of α-Fluoroketones Based on Palladiom-Catalyzed Decarboxylation Reactions of Allyl β-Keto Carboxylates
Fluorination of allyl β-keto carboxylates using N-fluoro-2,4,6-pyridinium triflate gave allyl α-fluoro-β-keto carboxylates.Reaction of allyl α-fluoro-β-keto carboxylates with formic acid in the presence of palladium-phosphine catalyst gave α-fluoro ketone
Shimizu, Isao,Ishii, Hirotoshi
p. 487 - 496
(2007/10/02)
Short Effective Synthesis of α-Fluoroketones by Palladium-Catalyzed Decarboxylation Reactions of Allyl α-Fluoro-β-keto Carboxylates
α-Fluoroketones, α-fluoro-α-allylketones, and α-fluoro-α,β-unsaturated ketones are synthesized by palladium-catalyzed decarboxylation reactions of allyl α-fluoro-β-keto carboxylates.
Shimizu, Isao,Ishii, Hirotoshi
p. 577 - 580
(2007/10/02)
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