- DIVINYL SULFIDE X. REACTION WITH MERCURIC CHLORIDE AND ACID HYDROLYSIS
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In a 20percent ethanol solution of mercuric chloride divinyl sulfide undergoes quantitative decomposition with the formation of acetaldehyde diethyl acetal, hydrochloric acid, and a complex salt of mercury.The hydrolysis of divinyl sulfide by hydrochloric acid in a water-dioxane medium leads to the production of hydrogen sulfide, acetaldehyde, 2,4,6-trimethyl-1,3,5-trithiane, and a small amount of acetaldehyde and thioacetaldehyde oligomers.The same products are formed during the hydrolysis of divinyl sulfide and an acidified solution of hydroxylamine hydrochloride; the acetaldehyde relased here is oximated.
- Gavrilova, G. M.,Gostevskaya, V. I.,Trofimov, B. A.,Amosova, S. V.
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p. 1613 - 1615
(2007/10/02)
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