Kinetics of reactions of thiolate ions with α-nitro β-substituted stilbenes in 50% Me2SO-50% water. Observation of the intermediate in nucleophilic vinylic substitution reactions
The kinetics of reactions of the type Ph(LG)C=CPh(NO2) + RS- →Ph(RS)C=CPh(NO2) + LG- were measured in 50% Me2SO-50% water (v/v) at 20 °C. Results on the following leaving group/nucleophile combination
Bernasconi, Claude F.,Fassberg, Julianne,Killion Jr., Robert B.,Rappoport, Zvi
p. 3169 - 3177
(2007/10/02)
Kinetics of the Reaction of β-Methoxy-α-nitrostilbene with Thiolate Ions. First Direct Observation of the Intermediate in a Nucleophilic Vinylic Substitution
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Bernasconi, Claude F.,Killion, Robert B.,Fassberg, Julianne,Rappoport, Zvi
p. 6862 - 6864
(2007/10/02)
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