A series of α-acyl formamidinium ions and their corresponding 1-electron reduced neutral radicals were synthesized, and their electrochemical properties were evaluated. These cations exhibit multi-electron redox processes that are highly electrochemically reversible at rapid scan rates (100 mV s-1), and the redox potentials were readily tailored by up to ~1.0 V, making them ideal candidates for organic radical-based charge storage materials.
Deardorff, Cassie L.,Eric Sikma,Rhodes, Christopher P.,Hudnall, Todd W.
supporting information
p. 9024 - 9027
(2016/07/21)
Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene
Using the nucleophilicity of NHCs and a NHCs, as well as the leaving group ability of the former, the carbon-carbon double bond of imidazol-2-ylidenes can be readily mono- and difunctionalized. These results provide also a new light on the formation of abnormal carbene adducts from classical unsaturated NHCs.
Mendoza-Espinosa, Daniel,Donnadieu, Bruno,Bertrand, Guy
supporting information; experimental part
p. 7264 - 7265
(2010/08/05)
More Articles about upstream products of 1228185-08-7