Cucurbituril slippage: Translation is a complex motion
(Figure presented) The kinetics of cucurbit[6]uril slippage along a polyaminated axle are highly dependent on even minor sterical alterations of the guest. According to in silico experiments, a plausible threading mechanism includes the deprotonation of the ammoniums prior to slippage, their tunneling through the cavitand as neutral amines, and their reprotonation upon exiting cucurbit[6]uril.
Ling, Xiaoxi,Samuel, E. Loic,Patchell, Devin L.,Masson, Eric
supporting information; experimental part
p. 2730 - 2733
(2010/08/06)
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