cas 122894-73-9, Ethyl 2,3,4,5-tetrafluorobenzoate | Articles data ｜lookchem

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122894-73-9

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Regioselective ortho-hydrodefluorination of pentafluorobenzoic acid by low-valent nickel complexes
2,3,4,5-Tetrafluorobenzoic and 3,4,5-trifluorobenzoic acids were prepared in high yields by reaction of C6F5COOH with zinc in the presence of NiCl2-2′-bipyridine (or 1,10-phenanthroline) complexes.
Adonin,Starichenko
p. 65 - 67
(2007/10/03)

Pyridonecarboxylic acids as antibacterial agents. VIII. Synthesis and structure-activity relationship of 7-(1-aminocyclopropyl)-4-oxo-1,8-naphthyridine-3-carboxylic acids and 7-(1-aminocyclopropyl)-4-oxoquinoline-3-carboxylic acids
4-Oxo-1,8-naphthyridine- and 4-oxoquinoline-3-carboxylic acids (2a, b and 3a-l) possessing a 1-aminocyclopropyl group at the 7-position have been synthesized and evaluated for in vitro antibacterial activities. The three quinolones (3d, h, i) exhibited potent antibacterial activities against both gram-positive and gram-negative bacteria, which are comparable to those of ciprofloxacin (CPFX) and ofloxacin (OFLX). Among the three compounds, the best pharmacological and pharmacokinetic profile was obtained with 3i, an OFLX analogue, which was considerably less toxic than three reference quinolones (1, CPFX, and OFLX).
Todo,Nitta,Miyajima,Fukuoka,Yamashiro,Nishida,Saikawa,Narita
p. 2063 - 2070
(2007/10/02)

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Chemical Properties

Appearance/Colour :white crystal powder
Boiling Point: 238.6 °C at 760 mmHg
Flash Point:95.3 °C
Density: 1.382 g/cm³
Refractive Index: 1.4440
PSA: 26.30000
LogP: 2.41970

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