Iron-catalyzed C-H and C-C bond cleavage: A direct approach to amides from simple hydrocarbons
Something functional: The title reaction proceeds in the presence of azide and water to deliver amides in high yields, and it can be used in a ring-expansion strategy to generate lactams. A mechanism is proposed based on experimental results. This reaction offers a new approach to functionalizing simple and readily available hydrocarbons. DDQ=2,3-dichloro-5,6-dicyano-1,4- benzoquinone. Copyright
Qin, Chong,Zhou, Wang,Chen, Feng,Ou, Yang,Jiao, Ning
supporting information; experimental part
p. 12595 - 12599
(2012/01/15)
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