- Synthesis of functionalized fluorinated terphenyls by site-selective Suzuki-Miyaura cross-coupling reactions of dibrominated fluorobenzenes
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A variety of fluorinated terphenyls were prepared by site-selective Suzuki-Miyaura cross-coupling reactions of dibrominated fluorobenzenes, such as 1,2-dibromo-3,5-difluorobenzene, 1,4-dibromo-2-fluorobenzene, 1,3-dibromo-4-fluorobenzene, and 1,2-dibromo-4-fluorobenzene.
- Sharif, Muhammad,Maalik, Aneela,Reimann, Sebastian,Feist, Holger,Iqbal, Jamshed,Patonay, Tamás,Villinger, Alexander,Langer, Peter
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- One-pot synthesis of difluorinated ortho -terphenyls by site-selective suzuki-miyaura reactions of 1,2-dibromo-3,5-difluorobenzene
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The Suzuki-Miyaura reaction of 1,2-dibromo-3,5-difluorobenzene with two equivalents of arylboronic acids gave difluorinated ortho-terphenyls. The reaction with one equivalent of arylboronic acid resulted in site-selective formation of 2-bromo-3,5-difluoro
- Sharif, Muhammad,Reimann, Sebastian,Villinger, Alexander,Langer, Peter
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experimental part
p. 913 - 916
(2010/07/06)
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