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123438-47-1

6-(benzyloxy)-7-Methoxy-1-Methyl-1,2,3,4-tetrahydroisoquinoline is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 123438-47-1 Structure

  • Basic information

    1. Product Name: 6-(benzyloxy)-7-Methoxy-1-Methyl-1,2,3,4-tetrahydroisoquinoline
    2. Synonyms:
    3. CAS NO:123438-47-1
    4. Molecular Formula: C18H21NO2
    5. Molecular Weight: 283.36484
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 123438-47-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 6-(benzyloxy)-7-Methoxy-1-Methyl-1,2,3,4-tetrahydroisoquinoline(CAS DataBase Reference)
    10. NIST Chemistry Reference: 6-(benzyloxy)-7-Methoxy-1-Methyl-1,2,3,4-tetrahydroisoquinoline(123438-47-1)
    11. EPA Substance Registry System: 6-(benzyloxy)-7-Methoxy-1-Methyl-1,2,3,4-tetrahydroisoquinoline(123438-47-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 123438-47-1(Hazardous Substances Data)

123438-47-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 123438-47-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,3,4,3 and 8 respectively; the second part has 2 digits, 4 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 123438-47:
(8*1)+(7*2)+(6*3)+(5*4)+(4*3)+(3*8)+(2*4)+(1*7)=111
111 % 10 = 1
So 123438-47-1 is a valid CAS Registry Number.

123438-47-1Relevant articles and documents

Synthesis, antitubulin, and antiproliferative sar of c3/c1-substituted tetrahydroisoquinolines

Dohle, Wolfgang,Leese, Mathew P.,Jourdan, Fabrice L.,Major, Meriel R.,Bai, Ruoli,Hamel, Ernest,Ferrandis, Eric,Kasprzyk, Philip G.,Fiore, Ann,Newman, Simon P.,Purohit, Atul,Potter, Barry V. L.

, p. 350 - 370 (2014/04/03)

The syntheses and antiproliferative activities of novel substituted tetrahydroisoquinoline derivatives and their sulfamates are discussed. Biasing of conformational populations through substitution on the tetrahydroisoquinoline core at C1 and C3 has a pro

Quinolizidines. VIII. Structure and Synthesis of the Alangium Alkaloid Alangicine: Syntheses of (+/-)- and (+)-Alangicines

Fujii, Tozo,Yamada, Koichiro,Minami, Shinzaburo,Yoshifuji, Shigeyuki,Ohba, Masashi

, p. 2583 - 2592 (2007/10/02)

The first total synthesis of alangicine (3), an Alangium lamarckii alkaloid, has been achieved in the form of a racemic modification by means of an initial alkaline hydrolysis of the (+/-)-tricyclic ester 6 and succeeding steps proceeding through the intermediates (+/-)-7, (+/-)-10, and (+/-)-9.A parallel synthetic route starting with the (-)-tricyclic ester 6, derived from (+)-cincholoipon ethyl ester (8), produced the chiral target molecule (+)-3 via the intermediates (-)-7, (-)-10, and 9.The identity of the synthetic (+)-3 with alangicine unequivocally established the structure and absolute stereochemistry of this alkaloid.The (13)C nuclear magnetic resonance spectra of (+/-)-alangicine (3) and the ipecac and Alangium alkaloid psychotrine (18) confirmed their endocyclic double bond structures in the dihydroisoquinoline moiety.Catalytic reductions of 11, (+/-)-12, and 15 using hydrogen and Pd-C were investigated, and the results have shown that hydrogenolysis of the benzyloxy group proceeds much faster than saturation of the endocyclic C=N bond.Keywords - alangicine; psychotrine; structure; absolute configuration; stereoselective synthesis; (13)C NMR; CD; benzyl ether; hydrogenolysis

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