Recycling a homogeneous catalyst through a light-controlled phase tag
(Figure Presented) A homogeneous ruthenium-carbene complex was tagged with a lightresponding nitrobenzospiropyran group to control its solubility through reversible conversion between its neutral (lipophilic) and ionic (lipophobic) states using light irradiation (see scheme; Mes = mesityl). This tagged complex has significant catalytic activity in ring-closing metathesis reactions and was recycled several times.
Liu, Guiyan,Wang, Jianhui
supporting information; experimental part
p. 4425 - 4429
(2010/08/07)
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