- SYNTHETIC INVESTIGATIONS IN THE FIELD OF INSECT ATTRACTANTS (SEX ATTRACTANTS). XIII. SYNTHESIS OF cis-6,cis-9-NONADECADIEN-3-ONE, A COMPONENT OF THE SEX PHEROMONE OF THE "VINE MOTH" Peribatodes rhomboidaria SCHIFF
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The reaction of (cis-3-tridecenyl)triphenylphosphonium bromide with the keto aldehyde 2-(3-oxopropyl)-2-ethyl-1,3-dioxolane protected at the keto group gave 2-(cis-3,cis-6-hexadecadienyl)-2-ethyl-1,3-dioxolane.The latter was converted by acid hydrolysis into cis-6,cis-9-nonadecadien-3-one, which is a component of the sex pheromone of the grape fly Peribatodes (= Boarmia) rhomboidaria Schiff.
- Kovalev, B. G.,Sorochinskaya, A. M.
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p. 1062 - 1065
(2007/10/02)
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