Thermal decomposition of new ruthenium(II) complexes containing N-alkylphenothiazines
Thermal decomposition of chlorpromazine hydrochloride (CP?HCl), trifluoperazine dihydrochloride (TF?2HCl) and thioridazine hydrochloride (TR?HCl), and the ruthenium complexes with dimethyl sulfoxide (dmso) of composition [RuCl2(dmso)4] and L[RuCl3(dmso) 3]?xEtOH, L = CP?HCl, TF?2HCl orTR?HCl is described. The phenothiazines are stable to temperature range of 200-280 °C with an increasing stability order of TF?2H Cl 3(dmso)3]Cl?EtOH. The compound crystallizes with one EtOH, evaporating in part at room temperature.
Sovilj, Sofija P.,Pokol, Gyoergy,Szecsenyi, Katalin Meszaros,Hollo, Berta,Krstic, Milena
p. 27 - 32
(2011/10/11)
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