125140-03-6

Basic information

• Product Name: (1aS,6R,7R,7aR,7bR)-6-hydroxy-7,7a-dimethyl-1a-[(2R)-2-methyloxiran-2-yl]-4,5,6,7,7a,7b-hexahydronaphtho[1,2-b]oxiren-2(1aH)-one
• Synonyms: Naphth[1,2-b]oxiren-2(1aH)-one,4,5,6,7,7a,7b-hexahydro-6-hydroxy-7,7a-dimethyl-1a-[(2R)-2-methyloxiranyl]-,(1aS,6R,7R,7aR,7bR)- (9CI)
• CAS NO: 125140-03-6
• Molecular Formula: C₁₅H₂₀O₄
• Molecular Weight: 264.3169
• Mol File: 125140-03-6.mol

Chemical Properties

• Boiling Point: 412.3°C at 760 mmHg
• Flash Point: 154.1°C
• Density: 1.29g/cm³
• Vapor Pressure: 1.61E-08mmHg at 25°C
• Refractive Index: 1.582
• CAS DataBase Reference: (1aS,6R,7R,7aR,7bR)-6-hydroxy-7,7a-dimethyl-1a-[(2R)-2-methyloxiran-2-yl]-4,5,6,7,7a,7b-hexahydronaphtho[1,2-b]oxiren-2(1aH)-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1aS,6R,7R,7aR,7bR)-6-hydroxy-7,7a-dimethyl-1a-[(2R)-2-methyloxiran-2-yl]-4,5,6,7,7a,7b-hexahydronaphtho[1,2-b]oxiren-2(1aH)-one(125140-03-6)
• EPA Substance Registry System: (1aS,6R,7R,7aR,7bR)-6-hydroxy-7,7a-dimethyl-1a-[(2R)-2-methyloxiran-2-yl]-4,5,6,7,7a,7b-hexahydronaphtho[1,2-b]oxiren-2(1aH)-one(125140-03-6)

Safety Data

• Hazardous Substances Data: 125140-03-6(Hazardous Substances Data)

Upstream product

• 88418-12-6 (3S,4R,4aR,5R,6R)-sporogen-AO 1 
• 134461-67-9 (3S,4R,4aR,5R,6R,1'R)-3-(1',2'-epoxy-1'-methylethyl)-6-t-butyldimethylsilyloxy-3,4-epoxy-4a,5-dimethyl-4,4a,5,6,7,8-hexahydro-2(3H)-naphthalenone 
• 122052-57-7 (3S,4R,4aR,5R,6R)-3-acetyl-6-tert-butyldimethylsilyloxy-3,4-epoxy-4,4a,5,6,7,8-hexahydro-4a,5-dimethyl-2(3H)naphthalenone 

Relevant articles and documents

Synthesis of oxygenated eremophilanes, gigantenone, phomenone and phaseolinone, phytotoxins from pathogenic fungi

Stereo selective synthesis of several oxygenated eremophilane sesquiterpenes as phytotoxins, (+)-gigantenone 1, (+)-phomenone 2 and (+)-phaseolinone 3, was achieved in short steps from (+)-sporogen-AO 1 (13-desoxyphomenone) 4.