Gold catalysis: Tandem reactions of diyne-diols and external nucleophiles as an easy access to tricyclic cage-like structures
Different diyne-diols composed of two terminal homopropargylic alcohol groups were prepared by bi-directional synthesis. Subjection of the syn diastereomers to NAC-gold catalysts (NAC=nitrogen acyclic carbene) in the presence of external nucleophiles such
Hashmi, A. Stephen K.,Buehrle, Miriam,Woelfle, Michael,Rudolph, Matthias,Wieteck, Marcel,Rominger, Frank,Frey, Wolfgang
supporting information; experimental part
p. 9846 - 9854
(2010/11/04)
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