PREPARATIVE SYNTHESIS OF C-(α-D-GLUCOPYRANOSYL)-ALKENES AND -ALKADIENES : DIELS-ALDER REACTION
The reaction of 2,3,4,6-tetra-O-benzyl-1-O-(p-nitrobenzoyl)-α-D-glucopyranose with (E)-penta-2,4-dienyltrimethylsilane and boron trifluoride etherate in acetonitrile afforded stereoselectivity (E)-5-(tetra-O-benzyl-α-D-glucopyranosyl)-1,3-pentadiene (1) i
Martin, Maria de Gracia Garcia,Horton, Derek
p. 223 - 230
(2007/10/02)
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