Chiral primary amine catalyzed asymmetric epoxidation of α-substituted acroleins
1,1-Disubstituted terminal alkenes remain challenging substrates in asymmetric epoxidation reactions. In this study, chiral primary amines are shown to catalyze the asymmetric epoxidation of α-substituted acroleins, a versatile type of 1,1-disubstituted t
Asymmetric epoxidation of α-substituted acroleins catalyzed by diphenylprolinol silyl ether
Asymmetric epoxidation of α-substituted acroleins with hydrogen peroxide has been catalyzed by diphenylprolinol diphenylmethylsilyl ether to afford α-substituted-β,β-unsubstituted-α,β-epoxy aldehyde with excellent enantioselectivity and the generation of
Bondzic, Bojan P.,Urushima, Tatsuya,Ishikawa, Hayato,Hayashi, Yujiro
supporting information; experimental part
p. 5434 - 5437
(2011/03/20)
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