125970-74-3

Basic information

• Product Name: allyl O-(3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-beta-Glup)(1-4)-O-(3,6-di-O-allyl-2-O-benzyl-beta-Manp)(1-4)-O-3,6-di-O-benzyl-2-deoxy-2-phthalimido-beta-Glup(1-4)-3-O-benzyl-2-deoxy-6-O-4-methoxyphenyl-2-phthalimido-beta-Glup
• Synonyms: allyl O-(3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-beta-Glup)(1-4)-O-(3,6-di-O-allyl-2-O-benzyl-beta-Manp)(1-4)-O-3,6-di-O-benzyl-2-deoxy-2-phthalimido-beta-Glup(1-4)-3-O-benzyl-2-deoxy-6-O-4-methoxyphenyl-2-phthalimido-beta-Glup
• CAS NO: 125970-74-3
• Molecular Formula: C₁₁₃H₁₁₁N₃O₂₅
• Molecular Weight: 1911.09554
• Mol File: 125970-74-3.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: allyl O-(3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-beta-Glup)(1-4)-O-(3,6-di-O-allyl-2-O-benzyl-beta-Manp)(1-4)-O-3,6-di-O-benzyl-2-deoxy-2-phthalimido-beta-Glup(1-4)-3-O-benzyl-2-deoxy-6-O-4-methoxyphenyl-2-phthalimido-beta-Glup(CAS DataBase Reference)
• NIST Chemistry Reference: allyl O-(3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-beta-Glup)(1-4)-O-(3,6-di-O-allyl-2-O-benzyl-beta-Manp)(1-4)-O-3,6-di-O-benzyl-2-deoxy-2-phthalimido-beta-Glup(1-4)-3-O-benzyl-2-deoxy-6-O-4-methoxyphenyl-2-phthalimido-beta-Glup(125970-74-3)
• EPA Substance Registry System: allyl O-(3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-beta-Glup)(1-4)-O-(3,6-di-O-allyl-2-O-benzyl-beta-Manp)(1-4)-O-3,6-di-O-benzyl-2-deoxy-2-phthalimido-beta-Glup(1-4)-3-O-benzyl-2-deoxy-6-O-4-methoxyphenyl-2-phthalimido-beta-Glup(125970-74-3)

Safety Data

• Hazardous Substances Data: 125970-74-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C113H111N3O25/c1-5-59-124-69-89-98(140-111-93(115-106(119)84-51-31-32-52-85(84)107(115)120)99(131-65-76-41-21-11-22-42-76)95(130-64-75-39-19-10-20-40-75)88(136-111)70-125-62-73-35-15-8-16-36-73)102(127-60-6-2)103(134-68-79-47-27-14-28-48-79)113(138-89)141-96-90(71-126-63-74-37-17-9-18-38-74)137-112(94(101(96)133-67-78-45-25-13-26-46-78)116-108(121)86-53-33-34-54-87(86)109(116)122)139-97-91(72-129-81-57-55-80(123-4)56-58-81)135-110(128-61-7-3)92(100(97)132-66-77-43-23-12-24-44-77)114-104(117)82-49-29-30-50-83(82)105(114)118/h5-58,88-103,110-113H,1-3,59-72H2,4H3/t88-,89-,90-,91-,92-,93-,94-,95-,96-,97-,98-,99-,100-,101-,102+,103+,110-,111+,112+,113+/m1/s1

Upstream product

• 125950-16-5 allyl O-(3,6-di-O-allyl-2-O-benzyl-β-D-mannopyranosyl)-(1->4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3-O-benzyl-2-deoxy-6-O-p-methoxyphenyl-2-phthalimido-β-D-glucopyranoside 
• 125946-65-8 3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl trichloroacetimidate 

Downstream Products

• 125946-71-6 O-(3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-O-(2-O-benzyl-β-D-mannopyranosyl)-(1->4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3-O-benzyl-2-deoxy-6-O-p-methoxyphenyl-2-phthalimido-D-glucopyranose 
• 125946-71-6 C₁₀₄H₉₉N₃O₂₅ 

Relevant articles and documents

Synthesis of an appropriately protected core glycotetraoside, a key intermediate for the synthesis of "bisected" complex-type glycans of a glycoprotein.

A stereocontrolled synthetic route to a glycotetraoside, allyl O-(3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-beta-D-glucopyranosyl)-(1--- -4)-O- (3,6-di-O-allyl-2-O-benzyl-beta-D-mannopyranosyl)-(1----4)-O-3, 6-di-O-benzyl-2-deoxy-2-phthalimido-beta-D-gluco

STEREOSELECTIVE SYNTHESIS OF A CORE GLYCOHEPTAOSE OF BISECTED BIANTENARRY COMPLEX TYPE GLYCAN OF GLYCOPROTEINS

A stereocontrolled synthesis of a core glycoheptaose of "bisected" complex type glycans of a glycoprotein was achieved by use of stereoselective glycosylation.