Gem-Difluoroallylation of Aldehydes and Ketones as a Convenient Route to α,α-Difluorohomoallylic Alcohols
In the presence of zinc, 3-bromo-3,3-difluoropropene or 3-iodo-1,1-difluoropropene reacted with carbonyl compounds to give the corresponding α,α-difluorohomoallylic alcohols in good yields at 0 deg C to room temperature.The reaction is applicable to aliph
Yang, Zhen-Yu,Burton, Donald J.
p. 1037 - 1041
(2007/10/02)
A facile preparation of gem-difluorohomoallylic alcohols[1]
The reaction of 3-bromo-3,3-difluoropropene with zinc powder in THF at 0°C to room temperature in the presence of aldehydes and ketones provides a useful, easily scaled up route to gem-difluorohomoallylic alcohols. α,β-Unsaturated aldehydes and ketones gi
Yang, Zhen-Yu,J. Burton, Donald
p. 339 - 343
(2007/10/02)
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