Quinidine thiourea-catalyzed aldol reaction of unactivated ketones: Highly enantioselective synthesis of 3-alkyl-3-hydroxyindolin-2-ones
New catalysis mechanism! The asymmetric aldol reaction of unactivated ketones and activated carbonyl compounds is realized with a quinidine-derived thiourea catalyst (see scheme), and involves an enolate mechanism instead of the widely used enamine mechan
Guo, Qunsheng,Bhanushali, Mayur,Zhao, Cong-Gui
experimental part
p. 9460 - 9464
(2011/02/22)
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