Control of ansa-zirconocene stereochemistry by reversible exchange of cyclopentadienyl and chloride ligands
The reaction of Li2[Me2Si(3-R-C5H3)2] salts with Zr{Me3SiN(CH2)3NSiMe3}Cl2(THF)2 in THF quantitatively afforded rac-Me2Si(3
Buck, Richard M.,Vinayavekhin, Nawaporn,Jordan, Richard F.
p. 3468 - 3469
(2008/04/18)
Hydroboration of Bis(alkenylcyclopentadienyl)zirconium Dichlorides
The reaction of allylcyclopentadienyllithium with 0.5 molar equivalents of MCl4(thf)2 (M = Zr, Hf) furnished the (η5-C5H4CH2CH=CH2)2MCl2 complexes 3a (Zr) and 3b (Hf), which cleanly added 9-borabicyclononane (9-BBN) to form 5/sup
Erker, Gerhard,Aul, Rainer
p. 1301 - 1310
(2007/10/02)
More Articles about upstream products of 126116-89-0