Azide-acetonitrile "click" reaction triggered by Cs2CO3: The atom-economic, high-yielding synthesis of 5-amino-1,2,3-triazoles
Medicinally important 5-amino-1,2,3-triazoles were synthesized using a novel Cs2CO3-catalyzed azide-acetonitrile[3 + 2]-cycloaddition. Aryl azides and aryl acetonitriles were employed in this transformation resulting in excellent yie
Design, synthesis and antimicrobial activities of 1,2,3-triazole derivatives
Fifteen 1-(4-substituted phenyl)-4-(4-bromophenyl)-5-(halo-o-hydroxyphenyl) imino-1,2,3-triazoles were designed and synthesized based on rational combination of 1,2,3-triazoles and (halo)o-hydroxyphenyl group according to the superposition principle of re
Zhao, Xu,Lu, Bo Wei,Lu, Jun Rui,Xin, Chun Wei,Li, Jian Fa,Liu, Ya
scheme or table
p. 933 - 935
(2012/09/07)
The Chemistry of 3-(α-Cyanobenzylidene)-1-phenyltriazenes and Their Conversion to Diarylmaleimides and Phenanthrene-9,10-dicarboximides
3-(α-Cyanobenzylidene)-1-phenyltriazine (3a), the product of thermolysis of 5-azido-1,4-diphenyl-1,2,3-triazole (2), is attacked by nucleophilic reagents at the azomethine carbon.Alcohols and phenol give rise to acetals of the N-phenylamidine of phenylgly
Smith, Peter A. S.,Friar, James Jeffrey,Resemann, Wolfgang,Watson, Andrew C.
p. 3351 - 3362
(2007/10/02)
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