Enantioselective additions of (trifluoromethyl)trimethylsilane to α-imino ketones derived from aryl glyoxals
Chemoselective additions of (trifluoromethyl)trimethylsilane to α-imino ketones derived from aryl glyoxals in the presence of a catalytic amount of enantiomerically pure ammonium bromides, derived from Cinchona alkaloids and K2CO3 le
Obijalska, Emilia,Mlostoń, Grzegorz,Six, Alice
p. 2462 - 2465
(2013/07/05)
Reactions of α-imino ketones derived from arylglyoxals with (trifluoromethyl)trimethylsilane; A new route to β-amino-α- trifluoromethyl alcohols
The reactions of α-imino ketones, derived from arylglyoxals, with (trifluoromethyl)trimethylsilane (CF3SiMe3) in DME solution, in the presence of catalytic amount of CsF, at room temperature, yield O-silylated β-imino alcohols in the
Mloston, Grzegorz,Obijalska, Emilia,Tafelska-Kaczmarek, Agnieszka,Zaidlewicz, Marek
experimental part
p. 1289 - 1296
(2011/02/22)
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