Influence iron-iron distance on the thermal decomposition of ammonium perchlorate. New catalysts for the highly efficient combustion of solid rocket propellant
Five homobimetallic compounds derived from indacene and p-phenylene ligands with different Fe–Fe distances have been synthesized. The catalytic effect on the thermal decomposition of Ammonium Perchlorate (AP) of each complex is analyzed, establishing comp
Arroyo, Juan Luis,Povea, Paula,Faúndez, Rodrigo,Camarada, María Belén,Cerda-Cavieres, Christopher,Abarca, Gabriel,Manriquez, Juan Manuel,Morales-Verdejo, Cesar
Linear or cross-shaped di(cyclopentadienyltitanium) compounds with aryl or heteroaryl spacers
The preparation of hexamethylated and hexabenzylated arylene or heteroarylene bridged dinuclear di(cyclopentadienyltitanium) compounds from the reaction of the corresponding hexachlorides with methyllithium or benzylmagnesium chloride is described. The spacers between the cyclopentadienyl rings consist of one, two or three phenylene groups, a dioctyloxyphenylene group or a 2,2′-bithienylene group. The corresponding hexachlorides and hexaisopropoxides have also been prepared.