Unexpected Formation of 3,3,3-Trifluoropropyltriphenylphosphonium Bromide and Subsequent Wittig-Olefination
An unusual rearrangement during the reaction of 1,1,1-trifluoroisopropyl bromide with triphenylphosphine leads to 3,3,3-trifluoropropyltriphenylphosphonium bromide, rendering the corresponding olefins accessible.
Ullmann, Joerg,Hanack, Michael
p. 685 - 687
(2007/10/02)
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