126560-51-8Relevant articles and documents
VINYL ETHERS CONTAINING AN ISOTHIOCYANATE GROUP. V. A NEW SYNTHESIS OF 2-(VINYLOXY)ETHYL ISOTHIOCYANATE
Nedolya, N. A.,Gerasimova, V. V.
, p. 1778 - 1780 (2007/10/02)
The thermolysis of methyl (2-vinyloxyethyl)dithiocarbamate in the presence of catalytic amounts of potassium hydroxide leads to the elimination of methanethiol and to the formation of 2-(vinyloxy)ethyl isothiocyanate with a yield of up to 70percent.
NEW DERIVATIVES OF DITHIOCARBAMIC ACID. II.* N-(2-VINYLOXYETHYL)DITHIOCARBAMATES AND THEIR TRANSFORMATIONS
Amosova, S. V.,Tarasova, O. A.,Ivanova, N. I.,Perzhabinskaya, L. I.,Sigalov, M. V.,et al.
, p. 1478 - 1484 (2007/10/02)
Previously unknown N-(2-vinyloxyethyl)dithiocarbamate esters were obtained with high yields by the reaction of potassium N-(-2-vinyloxyethyl)dithiocarbamate with equimolar amounts of organic halides in DMSO or ethanol.When heated above 100 deg C without a catalyst or in the presence of trifluoroacetic acid as catalyst at 20-60 deg C, the obtained esters undergo cyclization to 2-methyl-3--1,3-oxazolidines; the reaction is accompanied by the formation of 1,1-diethanes.The reaction of potassium N-(2-vinyloxyethyl)dithiocarbamate with acid chlorides in DMSO leads to 2-vinyloxyethyl isothiocyanate, which is obtained with a better yield by the cleavage of methyl N-(2-vinyloxyethyl)dithiocarbamate in toluene in the presence of catalytic amounts of potassium hydroxide.
