Design and implementation of an efficient synthetic approach to pyranosylated indolocarbazoles: Total synthesis of (+)-RK286c, (+)-MLR-52, (+)-staurosporine, and (-)-TAN-1030a
A total synthesis of the natural products (+)-staurosporine (2), (+)-RK286c (3), (-)-TAN-1030a (4), and (+)-MLR-52 (5) has been achieved. The synthetic strategy involves the stereoselective ring expansion of a furanosylated indolocarbazole [(+)-8] to a pyranosylated congener [(+)-12] that serves as a common intermediate in the production of 2-5.
Wood, John L.,Stoltz, Brian M.,Goodman, Steven N.,Onwueme, Kenolisa
p. 9652 - 9661
(2007/10/03)
Total synthesis of (+)-RK-286c, (+)-MLR-52, (+)-staurosporine, and (+)-K252a
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Wood, John L.,Stoltz, Brian M.,Goodman, Steven N.
p. 10656 - 10657
(2007/10/03)
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