HIGH-PRESSURE STOPPED-FLOW KINETICS OF PROTON-TRANSFER REACTION BETWEEN 4-NITROPHENYLNITROMETHANE AND 1,1',3,3'-TETRAMETHYLGUANIDINE IN APROTIC SOLVENTS
The proton-transfer reaction between title compounds was kinetically studied in toluene and dichloromethane at 25 deg C up to 1000 bar by the use of a high-pressure stopped-flow method.The volumes of activation were explainable on the basis of Kirkwood's electrostatic model.