A core challenge: The asymmetric formal syntheses of the title compounds have been accomplished. By using a modular approach, phenolic tosylamide 1 was synthesized through palladium cross-couplings (blue bonds), and its participation in a hypervalent iodine mediated oxidative coupling reaction (red bonds) enabled the construction of the challenging heterocyclic core of (-)-phalarine. Copyright
Ding, Hanfeng,Chen, David Y.-K.
supporting information; experimental part
p. 676 - 679
(2011/04/16)
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