Interplay of direct stereocontrol and dynamic kinetic resolution in a bifunctional amine thiourea catalyzed highly enantioselective cascade michael-michael reaction
Control is better: A novel chiral amine thiourea catalyzed, highly enantioselective Michael-Michael cascade process serves as a "one-pot" approach to synthetically and biologically significant chiral tetrahydrothiophenes (see scheme). Notably, an unpreced