THE REGIOCHEMISTRY OF THE (ETHOXYCARBONYL)NITRENE ADDITION REACTION TO SILOXYDIENES
1-Methoxy-3-methyl-1-siloxy-1,3-butadiene 1 adds (ethoxycarbonyl)nitrene generated by thermolysis to give the isomeric unsaturared amino esters 4 and 7; under photolytic conditions the main products are the isomers 4, 5, and 6. 2-Trimethylsiloxyfuran 8 reacts with the same nitrene to give only 10, either by thermolytic or photolytic route.
Loreto, M. Antonietta,Pellacani, Lucio,Tardella, Paolo A.
p. 5025 - 5028
(2007/10/02)
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