A convenient synthesis of aziridine-2-carboxylic esters
Optically active oxirane-2-carboxylic esters, prepared from allylic alcohols employing the Sharpless epoxidation, were treated with sodium azide.The azido alcohols obtained were subsequently converted into aziridine-2-carboxylic esters by reaction with triphenylphosphine, in good yields and with high optical purity.Various racemic oxirane-2-carboxylic esters were subjected to the same sequence of reactions.
Legters, Johan,Thijs, Lambertus,Zwanenburg, Binne
p. 1 - 15
(2007/10/02)
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