Models for nucleoside glycosylase enzymes. Evidence that the hydrolysis of β-d-ribofuranosides requires a "Backside" preassociation nucleophile
We have compared the pH-independent rates of glycosidic hydrolysis in a series of four fluorenone ketal derivatives of p-nitrophenyl β-D-ribofuranoside with each other and with that of p-nitrophenyl β-D-ribofuranoside itself. A syn-oriented carboxylate gr
Cherian, Xavier M.,Van Arman, Scott A.,Czarnik, Anthony W.
p. 4490 - 4498
(2007/10/02)
Experimental Support for Asp-52's Importance in Lysozyme Using a Carbohydrate-Based Enzyme Model. Acetal Hydrolysis Catalyzed by a "Stereoelectronically Correct" Carboxylate Group
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Cherian, Xavier M.,Arman, Scott A. Van,Czarnik, Anthony W.
p. 6566 - 6568
(2007/10/02)
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