127759-47-1Relevant articles and documents
Asymmetric rhodium-catalyzed hydrogenation meets gold-catalyzed cyclization: Enantioselective synthesis of 8-hydroxytetrahydroisoquinolines
Hashmi, A. Stephen K.,Haufe, Patrick,Schmid, Christoph,Nass, Andreas Rivas,Frey, Wolfgang
, p. 5376 - 5382 (2008/02/13)
Different furyl-substituted (Z)-dehydroamino acid derivatives were hydrogenated with the rhodium/Mandyphos(OMe)-system to give enantiomeric excesses between 80 and 98%. The absolute configuration of the newly formed stereogenic center was determined by an
Stereoselective synthesis of 3-heteroaromatic-substituted alanines
Croce, Piero Dalla,La Rosa, Concetta,Pizzatti, Enrica
, p. 2635 - 2642 (2007/10/03)
An asymmetric synthesis of (R)-3-heterocyclic-substituted alanines starting from (2S)-(+)-2,5-dihydro-3,6-dimethoxy-2-isopropylpyrazine (Schollkopf reagent) and heteroaromatic halogenomethyl derivatives via hydrolysis of intermediate adducts is reported.