Base-promoted selective aryl carbon-bromine bond cleavage by Iridium(III) porphyrin for Iridium(III) porphyrin aryl synthesis: A metalloradical Ipso addition-elimination mechanism
K2CO3 was found to promote selective aryl carbon-bromine bond (Ar-Br) cleavage by a high-valent iridium(III) porphyrin carbonyl chloride (IrIII(ttp)(CO)Cl, ttp = 5,10,15,20-tetra-p- tolylporphyrinato dianion) in benzene so
Cheung, Chi Wai,Chan, Kin Shing
p. 1768 - 1771
(2011/06/22)
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