Palladium-catalyzed dehydrogenative cross-couplings of benzazoles with azoles
Different enough: Palladium-catalyzed cross-couplings of benzazoles with imidazoles, oxazoles, and thiazoles furnish unsymmetrical 2,2′- bisheteroaryls in high yield (see scheme). These oxidative Ci-C bond formations use the selective cleavage of the Ci-H bond at C2 in the two coupling partners and are robust enough to be conducted under normal air atmosphere.
Han, Wei,Mayer, Peter,Ofial, Armin R.
supporting information; experimental part
p. 2178 - 2182
(2011/04/17)
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