Evidence for stereoelectronic control in the epoxidation of sterically unbiased 3,3-diarylcyclopentenes
Epoxidations of the sterically unbiased olefin, 3-(4-X-phenyl)-3-phenylcyclopentene (X = NO2, Br, Cl, OCH3) with peracetic acid have been found to proceed with up to 73.27 stereoselectivity. Stereochemistry of the products was determ
Halterman,McEvoy
p. 753 - 756
(2007/10/02)
Diastereoselectivity in the reduction of sterically unbiased 2,2-diarylcyclopentanones
Reduction of sterically unbiased 2-phenyl-2-(4-X-phenyl)cyclopentanones 1 (X = NO2, Br, Cl, OCH3, OH, NH2) with either sodium borohydride in methanol or lithium borohydride in tetrahydrofuran at 0°C produced diastereomeric
Halterman, Ronald L.,McEvoy, Marjorie A.
p. 6690 - 6695
(2007/10/02)
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