Synthesis of (1R,2R)-DPEN-derived triazolium salts and their application in asymmetric intramolecular Stetter reactions
A series of novel chiral triazolium salts has been synthesized from readily available (1R,2R)-DPEN and found to be efficient for the enantioselective intramolecular Stetter reaction. With 10 mol% of the catalyst, the intramolecular Stetter reaction was re
(1R,2R)-DPEN-derived triazolium salts for enantioselective oxodiene Diels-Alder reactions
Enantioselective oxodiene Diels-Alder reactions catalyzed by (1R,2R)-DPEN-derived triazolium salts were realized successfully. With 0.5 mol % of (1R,2R)-DPEN-derived triazolium salt C and 150 mol % of Et3N, the reactions of various α-chloroalde
Rong, Zi-Qiang,Jia, Min-Qiang,You, Shu-Li
scheme or table
p. 9329 - 9333
(2011/12/14)
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