Asymetric Electrophilic α-Amidoalkylation, VII: Generation, Crystal Structure, and Trapping Reactions of a Chiral 6,7-Dimethoxy-1,2,3,4-tetrahydroisoquinoline Derived N-Acyliminium Ion
The camphanic acid amide 4 has efficiently been oxidized with triphenylcarbenium tetrafluoroborate (3) to yield the chiral N-acyliminium ion 1.Trapping reactions of 1 with the silyl nucleophiles 7a-c and 10a-f proceeded with stereoselective bond formation
Wanner, Klaus Th.,Praschak, Ilona,Nagel, Ulrich
p. 335 - 350
(2007/10/02)
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