Chelation Control by Phosphite Esters in Rhodium Catalysed Hydroformylation
Phosphite esters can be used to give excellent regiocontrol in rhodium catalysed hydroformylation reactions of alkenes and in addition excellent stereocontrol in the reactions of some cyclohexenyl phosphites.
Jackson, W. Roy,Perlmutter, Patrick,Tasdelen, E. Elizabeth
The Stereochemistry of Organometallic Compounds. XXXVIII. Regio- and Stereo-control in the Rhodium-Catalysed Hydroformylation of Some Alkenyl Phosphites
Excellent regiocontrol is achieved in the rhodium-catalysed hydroformylation of some alkenyl phosphites, and good stereocontrol is obtained in the hydroformylation of some cyclohexenyl phosphites.The stereochemical results have implications for the mechanism of these rhodium-catalysed reactions.
Jackson, W. Roy,Moffat, Mark R.,Perlmutter, Patrick,Tasdelen, E. Elizabeth
p. 823 - 834
(2007/10/02)
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