A single phosphine ligand allows palladium-catalyzed intermolecular C-O bond formation with secondary and primary alcohols
Forging a bond: An efficient, general palladium catalyst for C-O bond-forming reactions of secondary and primary alcohols with a range of aryl halides has been developed using the ligand 1. Heteroaryl halides, and for the first time, electron-rich aryl halides can be coupled with secondary alcohols. A diverse set of substrate combinations are possible with just a single ligand, thus obviating the need to survey multiple ligands. Copyright
Wu, Xiaoxing,Fors, Brett P.,Buchwald, Stephen L.
supporting information; experimental part
p. 9943 - 9947
(2011/12/05)
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