Conjugate addition of radicals generated from diacyloxyiodobenzenes to dehydroamino acid derivatives; a synthesis of diaminopimelic acid analogues
Radical decomposition of bis((2S)-N-benzyloxycarbonyl-2-aminopentan-5-carboxy-1-methyl ester)iodobenzene followed by decarboxylation and subsequent conjugate addition with a series of selectively protected dehydroamino acids leads to new analogues of diam
Diastereoselective Radical Addition to Derivatives of Dehydroalanine and of Dehydrolactic Acid
The cyclic methylene compounds (1)-(3) undergo diastereoselective free radical addition when treated with alkylmercury hydride or alkyl iodide/tributylstannane to give products useful for the enantioselective synthesis of α-amino and α-hydroxy acids.
Beckwith, Athelstan L. J.,Chai, Christina L. L.
p. 1087 - 1088
(2007/10/02)
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