130973-44-3Relevant articles and documents
Asymmetric metal-catalysed epoxidation of electron-deficient olefins
Bailey,Staton,Ashton,Marko,Ollis
, p. 495 - 509 (2007/10/02)
The SYN diastereospecific epoxidation of acyclic β-hydroxyketones (β-hydroxyacrylates) and cyclic β-hydroxyketones using titanium and vanadium catalysts is reported. Some initial results on the asymmetric epoxidation of these systems using the Sharpless t
Stereoselective epoxidation of hydroxyenones. The synthesis of the sidechain of clerocidin
Bailey,Marko,Ollis,Rasmussen
, p. 4509 - 4512 (2007/10/02)
The sidechains of clerocidin 1 and terpentecin 2 contain a unique chiral assembly [C5H5O4]. Models for the stereospecific synthesis of this structural feature are reported.