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13099-35-9

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Synthesis and Th1-immunostimulatory activity of α-galactosylceramide analogues bearing a halogen-containing or selenium-containing acyl chain
A novel series of CD1d ligand α-galactosylceramides (α-GalCers) were synthesized by incorporation of the heavy atoms Br and Se in the acyl chain backbone of α-galactosyl-N-cerotoylphytosphingosine. The synthetic analogues are potent CD1d ligands and stimulate mouse invariant natural killer T (iNKT) cells to selectively enhance Th1 cytokine production. These synthetic analogues would be efficient X-ray crystallographic probes to disclose precise atomic positions of alkyl carbons and lipid–protein interactions in KRN7000/CD1d complexes.
Hossain, Md. Imran,Hanashima, Shinya,Nomura, Takuto,Lethu, Sébastien,Tsuchikawa, Hiroshi,Murata, Michio,Kusaka, Hiroki,Kita, Shunsuke,Maenaka, Katsumi
p. 3687 - 3695
(2016/07/20)

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Chemical Properties

Melting Point: 72-74°C
Boiling Point: 436.2 °C at 760 mmHg
Flash Point:217.6 °C
Density: 1.102g/cm³
Vapor Pressure: 7.9E-09mmHg at 25°C
Refractive Index: 1.48
PKA: 4.78±0.10(Predicted)
PSA: 37.30000
LogP: 6.31740

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