- Heteroarylation of anthraquinone-triflate by Suzuki cross-coupling
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The reactivity of the 4-pyridylboronate 5a for PdCl2(dppf)catalysed cross-coupling reaction with an anthraquinone triflate is presented, and compared with its 2-thienyl- and phenylboronic analogues. Best results have been obtained on a small sc
- Coudret, Christophe,Mazenc, Valerie
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- A cross-dipole stacking molecule of an anthracene derivative: Integrating optical and electrical properties
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Cross-dipole stacking has been addressed as a preferred motif for solid state emission, but inefficient for charge transport. Here we synthesize a new anthracene derivative, which adopts cross-stacking in the solid state with a solid state fluorescence up to 77.3% and a hole mobility of 1.47 cm2 V-1 s-1, integrating optical and electrical properties successfully. As far as we know, it is the first report of organic field-effect transistors based on cross-dipole stacking molecules.
- Liu, Jie,Meng, Lingqiang,Zhu, Weigang,Zhang, Congcong,Zhang, Hantang,Yao, Yifan,Wang, Zongrui,He, Ping,Zhang, Xiaotao,Wang, Ying,Zhen, Yonggang,Dong, Huanli,Yi, Yuanping,Hu, Wenping
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- 2,6-Diaryl-9,10-anthraquinones as models for electron-accepting polymers
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Anthraquinone derivatives have been little used in microelectronics though they are attractive scaffolds due to their electron-accepting properties. As part of a preliminary study, a series of conjugated anthraquinone derivatives has been synthesised. The
- Gautrot, Julien E.,Hodge, Philip,Cupertino, Domenico,Helliwell, Madeleine
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- Aggregation-induced emission enhancement based on 11,11,12,12,-tetracyano- 9,10-anthraquinodimethane
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By introducing phenyl groups into the 2- and 6-positions of 11,11,12,12-tetracyano-9,10-anthraquinodimethane, a material (dP-TCAQ) with aggregation-induced emission enhancement (AEE) characteristics was synthesized. The AEE phenomenon was explained by analysis of its solid-state packing mode. To our best knowledge, this is the first report regarding 11,11,12,12-tetracyano- 9,10-anthraquinodimethane with AEE behaviour.
- Liu, Jie,Meng, Qing,Zhang, Xiaotao,Lu, Xiuqiang,He, Ping,Jiang, Lang,Dong, Huanli,Hu, Wenping
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p. 1199 - 1201
(2013/03/13)
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- ANTHRACENE DERIVATIVES AND ORGANIC ELECTROLUMINESCENT DEVICES MADE BY USING THE SAME
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An anthracene derivative represented by the following general formula (1) which enables an organic electroluminescence device to exhibit a great efficiency of light emission and uniform light emission even at high temperatures since crystallization is suppressed and no thermal decomposition takes place during vapor deposition and an organic electroluminescence device utilizing the derivative, are provided. [Ar represents a group represented by the following general formula (2): (L1 and L2 each represent a substituted or unsubstituted methylene group, ethylene group or the like, and at least one of them is present), Ar' represents a substituted or unsubstituted aryl group having 6 to 50 nuclear carbon atoms, X represent an alkyl group or the like, a and b each represent an integer of 0 to 4, and n represents an integer of 1 to 3.]
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Page/Page column 21-22
(2010/02/11)
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- Synthesis of anthraquinone derivatives by palladium-catalyzed coupling of triflates with stannanes
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The palladium-catalyzed coupling of hydroxyanthraquinone triflates with stannanes provides an efficient entry into substituted anthraquinones under neutral conditions.
- Tamayo, Nuria,Echavarren, Antonio M.,Paredes, M. Carmen,Farina, Francisco,Noheda, Pedro
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p. 5189 - 5192
(2007/10/02)
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