A general copper-BINAP-catalyzed asymmetric propargylation of ketones with propargyl boronates
An operationally simple copper-BINAP-catalyzed, highly enantioselective propargylation of ketones is presented. The methodology was developed as an enantioselective process for methyl ethyl ketone and shown to be applicable to a wide variety of prochiral
Fandrick, Keith R.,Fandrick, Daniel R.,Reeves, Jonathan T.,Gao, Joe,Ma, Shengli,Li, Wenjie,Lee, Heewon,Grinberg, Nelu,Lu, Bruce,Senanayake, Chris H.
supporting information; experimental part
p. 10332 - 10335
(2011/09/13)
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